Before entering the Upper East Side, both Leighton and Ed were singers. "I've always done [music]," Leighton said. Fans can hear her on the soundtrack for the movie Drive Thru. The actress hopes to release her own album next year and describes her music as "a good mixture of hip-hop sounding" and "very vibe-y."

And even before Chuck had his eyes on Blair, Ed belonged to the unsigned, London-based, punk band, The Filthy Youth. Two of his songs, "Come Flash All You Ladies" and "Orange," were actually played during GG!

P.S. Last night Ed was spotted kissing Drew Barrymore! Do you think they make a cute couple?